Actually, what you probably meant was Singleton, not simpleton
But I don't think that's what you need for such a task. You can apply a theme at view load, depending on what the view contains it could be just a few lines to set the colors of objects, or load different images from the bundle.
You can use NSUserDefaults to save the name of the theme the user chose, and when you are about the load the view, check what is saved and load the right theme.